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https://hdl.handle.net/10356/95800
Title: | Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers | Authors: | Jiang, Yaojia Chan, Wei Chuen Park, Cheol-Min |
Issue Date: | 2012 | Source: | Jiang, Y., Chan, W. C., & Park, C. M. (2012). Expedient Synthesis of Highly Substituted Pyrroles via Tandem Rearrangement of α-Diazo Oxime Ethers. Journal of the American Chemical Society, 134(9), 4104-4107. | Series/Report no.: | Journal of the American chemical society | Abstract: | An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields. | URI: | https://hdl.handle.net/10356/95800 http://hdl.handle.net/10220/11202 |
DOI: | 10.1021/ja300552c | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2012 American Chemical Society. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | SPMS Journal Articles |
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