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https://hdl.handle.net/10356/96145
Title: | Asymmetric synthesis of enaminophosphines via palladacycle-catalyzed addition of Ph2PH to α,β-unsaturated imines | Authors: | Pullarkat, Sumod A. Huang, Yinhua Chew, Renta Jonathan Li, Yongxin Leung, Pak-Hing |
Issue Date: | 2012 | Source: | Huang, Y., Chew, R. J., Pullarkat, S. A., Li, Y., & Leung, P.-H. (2012). Asymmetric Synthesis of Enaminophosphines via Palladacycle-Catalyzed Addition of Ph 2 PH to α,β-Unsaturated Imines . The Journal of Organic Chemistry, 77(16), 6849-6854. | Series/Report no.: | The journal of organic chemistry | Abstract: | A highly reactive, chemo- and enantioselective addition of diphenylphosphine to α,β-unsaturated imines catalyzed by a palladacycle has been developed, thus providing the access to a series of chiral tertiary enaminophosphines in high yields. A putative catalytic cycle has also been proposed. | URI: | https://hdl.handle.net/10356/96145 http://hdl.handle.net/10220/17050 |
DOI: | 10.1021/jo300893s | Schools: | School of Physical and Mathematical Sciences | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | SPMS Journal Articles |
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