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Title: | The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water | Authors: | Lee, Jia Ying Fan, Wai Yip Mak, Garvin Kar Hang Leong, Weng Kee |
Issue Date: | 2012 | Source: | Lee, J. Y., Fan, W. Y., Mak, K. H. G., & Leong, W. K. (2013). The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water. Journal of Organometallic Chemistry, 724, 275-280. | Series/Report no.: | Journal of organometallic chemistry | Abstract: | The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. This reaction was found to be photochemically activated, and a possible pathway involving radical intermediates has been proposed and studied experimentally and computationally. | URI: | https://hdl.handle.net/10356/99564 http://hdl.handle.net/10220/17390 |
ISSN: | 0022-328X | DOI: | 10.1016/j.jorganchem.2012.11.030 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2012 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of organometallic chemistry, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.jorganchem.2012.11.030]. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Journal Articles |
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The Formation of Aldehydes from the Photochemically Activated Reaction.pdf | 207.04 kB | Adobe PDF | View/Open |
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