Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/102559
Title: | Near-infrared responsive conjugated polymers to 1.5 μm and beyond : synthesis and electrochromic switching application | Authors: | Tang, Tao Ding, Guoqiang Lin, Tingting Chi, Hong Liu, Chen Lu, Xuehong Wang, FuKe He, Chaobin |
Keywords: | Materials Science and Engineering | Issue Date: | 2013 | Source: | Tang, T., Ding, G., Lin, T., Chi, H., Liu, C., Lu, X., et al. (2013). Near-Infrared Responsive Conjugated Polymers to 1.5 μm and Beyond: Synthesis and Electrochromic Switching Application. Macromolecular Rapid Communications, 34(5), 431-436. | Series/Report no.: | Macromolecular rapid communications | Abstract: | Azulene-containing conjugated polymers with near-infrared absorption up to 1.5 μm and beyond are achieved by treating with trifluoroacetic acid (TFA). Density functional theory calculations reveal that the near-infrared absorption arises from a strong intramolecular charge transfer transition on the polymer backbone, and the near-infrared absorption can be tuned by the degree of protonation. Furthermore, TFA treated polymers show a ten-fold enhancement in electrochromic contrast and significantly improved switching stability, suggesting that these polymers are promising candidates for fabrication of the first generation organic near-infrared devices. | URI: | https://hdl.handle.net/10356/102559 http://hdl.handle.net/10220/19054 |
ISSN: | 1022-1336 | DOI: | 10.1002/marc.201200695 | Schools: | School of Materials Science & Engineering | Rights: | © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | MSE Journal Articles |
SCOPUSTM
Citations
20
25
Updated on Mar 6, 2024
Web of ScienceTM
Citations
20
22
Updated on Oct 31, 2023
Page view(s) 20
759
Updated on Mar 19, 2024
Google ScholarTM
Check
Altmetric
Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.