Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/105792
Title: Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds
Authors: Medvedev, Alexander G.
Mikhaylov, Alexey A.
Churakov, Andrei V.
Prikhodchenko, Petr V.
Lev, Ovadia
Keywords: DRNTU::Engineering::Materials
Issue Date: 2012
Source: Medvedev, A. G., Mikhaylov, A. A., Churakov, A. V., Prikhodchenko, P. V., & Lev, O. (2012). Ammonium and caesium carbonate peroxosolvates: supramolecular networks formed by hydrogen bonds. Acta crystallographica section C crystal structure communications, 68(3), i20-i24.
Series/Report no.: Acta crystallographica section C crystal structure communication
Abstract: Diammonium carbonate hydrogen peroxide monosolvate, 2NH4+·CO32-·H2O2, (I), and dicaesium carbonate hydrogen peroxide tris­olvate, 2Cs+·CO32-·3H2O2, (II), were crystallized from 98% hydrogen peroxide. In (I), the carbonate anions and peroxide solvent mol­ecules are arranged on twofold axes. The peroxide mol­ecules act as donors in only two hydrogen bonds with carbonate groups, forming chains along the a and c axes. In the structure of (II), there are three independent Cs+ ions, two of them residing on twofold axes, as are two of the four peroxide mol­ecules, one of which is disordered. Both structures comprise complicated three-dimensional hydro­gen-bonded networks.
URI: https://hdl.handle.net/10356/105792
http://hdl.handle.net/10220/20922
ISSN: 0108-2701
DOI: 10.1107/S0108270112006701
Schools: School of Materials Science & Engineering 
Rights: © 2012 International Union of Crystallography. This paper was published in Acta Crystallographica Section C Crystal Structure Communications and is made available as an electronic reprint (preprint) with permission of International Union of Crystallography. The paper can be found at the following official DOI: [http://dx.doi.org/10.1107/S0108270112006701].  One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles

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