| dc.contributor.author |
Liu, Yu. |
| dc.contributor.author |
Han, Jian Rong. |
| dc.contributor.author |
Zhao, Yanli. |
| dc.contributor.author |
Zhang, Heng Yi. |
| dc.contributor.author |
Duan, Zhong Yu. |
| dc.date.accessioned |
2011-10-03T08:01:05Z |
| dc.date.available |
2011-10-03T08:01:05Z |
| dc.date.copyright |
2005 |
| dc.date.issued |
2011-10-03 |
| dc.identifier.citation |
Liu, Y., Han, J. R., Zhao, Y. L., Zhang, H. Y., & Duan, Z. Y. (2005). Synthesis of some selenacrown ethers and the thermodynamic origin of their complexation with C60. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 51, 191-198. |
| dc.identifier.uri |
http://hdl.handle.net/10220/7138 |
| dc.description.abstract |
Two new selenacrown ethers, i.e., N,N'-dimethyl-1,11-diaza-4,8,14,18,-tetraselenacycloicosane (1) and 7,11-
diseleno-2,3,15,16,-dibenzo-1,4,14,17,20,23-hexaoxacyclopentacosane (2), have been synthesized and characterized by elemental analysis and UV, and 1H-NMR spectroscopy. An X-ray crystallographic structure was obtained for 1. UV-spectrophotometric titrations have been performed in CCl4 solution at 25–50 °C to obtain the complex stability
constants (Ks) and the thermodynamic parameters (ΔH° and TΔS°) for the stoichiometric 1:1 complexation of
[60]-fullerene (C60) with the crown ethers 1–4. The obtained Ks values together with that reported for
dicyclohexano-24-crown-8 (5) reveal that, the more the heteroatom numbers in crown ether ring are, and the larger
the cavity sizes of crown ethers are, the higher the Ks values for complexation with C60 are. Thermodynamically, the
complexation of C60 with 1–5 is absolutely enthalpy-driven in CCl4, while the complex stability is governed by the
entropy term. |
| dc.format.extent |
8 p. |
| dc.language.iso |
en |
| dc.relation.ispartofseries |
Journal of inclusion phenomena and macrocyclic chemistry |
| dc.rights |
© 2005 Springer. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Inclusion Phenomena and Macrocyclic Chemistry, Springer. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: http://dx.doi.org/10.1007/s10847-005-0662-6. |
| dc.subject |
DRNTU::Science::Biological sciences::Biochemistry. |
| dc.title |
Synthesis of some selenacrown ethers and the thermodynamic origin of their complexation with C60. |
| dc.type |
Journal Article |
| dc.contributor.school |
School of Physical and Mathematical Sciences |
| dc.identifier.doi |
http://dx.doi.org/10.1007/s10847-005-0662-6 |
| dc.description.version |
Accepted version |
| dc.identifier.rims |
159706 |
