mirage

A light-stimulated molecular switch driven by radical–radical interactions in water

DSpace/Manakin Repository

 

Search DR-NTU


Advanced Search Subject Search

Browse

My Account

A light-stimulated molecular switch driven by radical–radical interactions in water

Show full item record

Title: A light-stimulated molecular switch driven by radical–radical interactions in water
Author: Li, Hao; Fahrenbach, Albert C.; Coskun, Ali; Zhu, Zhixue; Barin, Gokhan; Zhao, Yanli; Botros, Youssry Y.; Sauvage, Jean-Pierre.; Stoddart, J. Fraser
Copyright year: 2011
Abstract: A redox-controllable bistable [2]rotaxane has been synthesized using templation and click chemistry. With assistance from a sacrificial electron donor, light-triggered switching through numerous cycles can be initiated by radical-pairing interactions between the reduced forms of the cyclophane and the bipyridinium unit in aqueous solution in the absence of air. In the presence of air (O2), the interactions are reset by donor–acceptor charge transfer.
Subject: DRNTU::Science::Chemistry.
Type: Journal Article
Series/ Journal Title: Angewandte chemie (International edition)
School: School of Physical and Mathematical Sciences
Rights: © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Files in this item

Files Size Format View

There are no files associated with this item.

   

DOI Query

- Get published version (via Digital Object Identifier)
   

This item appears in the following Collection(s)

Show full item record

Statistics

Total views

All Items Views
A light-stimulated molecular switch driven by radical–radical interactions in water 930

Total downloads

All Bitstreams Views
6782_ftp.pdf 5

Top country downloads

Country Code Views
Singapore 3

Top city downloads

city Views
Singapore 3