| dc.contributor.author |
Li, Hao. |
| dc.contributor.author |
Fahrenbach, Albert C. |
| dc.contributor.author |
Coskun, Ali. |
| dc.contributor.author |
Zhu, Zhixue. |
| dc.contributor.author |
Barin, Gokhan. |
| dc.contributor.author |
Zhao, Yanli. |
| dc.contributor.author |
Botros, Youssry Y. |
| dc.contributor.author |
Sauvage, Jean-Pierre. |
| dc.contributor.author |
Stoddart, J. Fraser. |
| dc.date.accessioned |
2012-01-11T01:29:44Z |
| dc.date.available |
2012-01-11T01:29:44Z |
| dc.date.copyright |
2011 |
| dc.date.issued |
2012-01-11 |
| dc.identifier.citation |
Li, H., Fahrenbach, A. C., Coskun, A., Zhu, Z., Barin, G., Zhao, Y. L., et al. (2011). A Light-Stimulated Molecular Switch Driven by Radical–Radical Interactions in Water. Angewandte Chemie International Edition, 50(30), 6782-6788. |
| dc.identifier.uri |
http://hdl.handle.net/10220/7456 |
| dc.description.abstract |
A redox-controllable bistable [2]rotaxane has been synthesized using templation and click chemistry. With assistance from a sacrificial electron donor, light-triggered switching through numerous cycles can be initiated by radical-pairing interactions between the reduced forms of the cyclophane and the bipyridinium unit in aqueous solution in the absence of air. In the presence of air (O2), the interactions are reset by donor–acceptor charge transfer. |
| dc.language.iso |
en |
| dc.relation.ispartofseries |
Angewandte chemie (International edition) |
| dc.rights |
© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
| dc.subject |
DRNTU::Science::Chemistry. |
| dc.title |
A light-stimulated molecular switch driven by radical–radical interactions in water. |
| dc.type |
Journal Article |
| dc.contributor.school |
School of Physical and Mathematical Sciences |
| dc.identifier.doi |
http://dx.doi.org/10.1002/anie.201102510 |
| dc.identifier.rims |
162615 |
