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Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes.

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Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes.

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Title: Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes.
Author: Zhang, Junmin.; Tiwari, Bhoopendra.; Xing, Chong.; Chen, Xingkuan.; Chi, Robin Yonggui.
Copyright year: 2012
Abstract: An enantioselective and direct oxidative coupling of aldehydes to tertiary amines to give β-amino alcohols is described. Catalyzed by copper(II), the reaction proceeds to give a racemic mixture of products; however, by using a combination of copper(II) and a chiral amine catalyst, the reaction gives the desired products with high enantioselectivity.
Subject: DRNTU::Science::Mathematics::Applied mathematics.
Type: Journal Article
Series/ Journal Title: Angewandte chemie international edition
School: School of Physical and Mathematical Sciences
Rights: © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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