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Title:
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Enantioselective oxidative cross-dehydrogenative coupling of tertiary amines to aldehydes.
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Author:
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Zhang, Junmin.; Tiwari, Bhoopendra.; Xing, Chong.; Chen, Xingkuan.; Chi, Robin Yonggui.
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Copyright year:
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2012 |
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Abstract:
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An enantioselective and direct oxidative coupling of aldehydes to tertiary amines to give β-amino alcohols is described. Catalyzed by copper(II), the reaction proceeds to give a racemic mixture of products; however, by using a combination of copper(II) and a chiral amine catalyst, the reaction gives the desired products with high enantioselectivity. |
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Subject:
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DRNTU::Science::Mathematics::Applied mathematics. |
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Type:
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Journal Article |
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Series/ Journal Title:
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Angewandte chemie international edition |
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School:
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School of Physical and Mathematical Sciences |
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Rights:
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© 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
