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Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2

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Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2

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Title: Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2
Author: Tiwari, Bhoopendra; Zhang, Junming; Chi, Robin Yonggui
Copyright year: 2012
Abstract: Giving the metal the boot: The title reaction provides facile access to functionalized chiral ketones from chiral α,α′-disubstituted aldehydes in the presence of molecular oxygen (see scheme). The CC bond-cleavage approach offers an alternative or better method relative to the typical bond-forming strategies used in synthesizing chiral ketones.
Subject: DRNTU::Engineering::Chemical engineering::Biochemical engineering
Type: Journal Article
Series/ Journal Title: Angewandte chemie international edition
School: School of Physical and Mathematical Sciences
Rights: © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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