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Title:
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Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2.
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Author:
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Tiwari, Bhoopendra.; Zhang, Junming.; Chi, Robin Yonggui.
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Copyright year:
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2012 |
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Abstract:
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The title reaction provides facile access to functionalized chiral ketones from chiral α,α′-disubstituted aldehydes in the presence of molecular oxygen. The C-C bond-cleavage approach offers an alternative or better method relative to the typical bond-forming strategies used in synthesizing chiral ketones. |
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Subject:
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DRNTU::Engineering::Chemical engineering::Biochemical engineering. |
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Type:
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Journal Article |
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Series/ Journal Title:
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Angewandte chemie international edition |
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School:
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School of Physical and Mathematical Sciences |
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Rights:
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© 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |