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Brønsted acid catalyzed α-alkylation of aldehydes with diaryl methyl alcohols

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Brønsted acid catalyzed α-alkylation of aldehydes with diaryl methyl alcohols

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Title: Brønsted acid catalyzed α-alkylation of aldehydes with diaryl methyl alcohols
Author: Xing, Chong; Sun, Hui; Zhang, Junmin; Li, Guohui; Chi, Robin Yonggui
Copyright year: 2011
Abstract: A proton does the two jobs: Brønsted acids alone catalyze the α-alkylation of aldehydes with diaryl alcohols. In this type of transformation, the acid-catalysis approach offers a broader substrate scope compared to the previously used enamine catalysis methods. The acid plays two important roles: one is to mediate the alcohol dehydration for carbocation formation; the other is to accelerate the rate-determining aldehyde enolization.
Type: Journal ArticleDRNTU::Engineering::Chemical engineering::Biochemical engineering.
Series/ Journal Title: Chemistry - a European journal
School: School of Physical and Mathematical Sciences
Rights: © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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