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Studies on the magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2 (HOBz-Benzoic acid)

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Studies on the magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2 (HOBz-Benzoic acid)

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dc.contributor.author Wang, Guoxiong
dc.contributor.author Zhang, Hua
dc.contributor.author Chen, Yao
dc.contributor.author Yao, Tianyang
dc.contributor.author Fu, Degang
dc.date.accessioned 2012-09-19T04:38:37Z
dc.date.available 2012-09-19T04:38:37Z
dc.date.copyright 1996
dc.date.issued 2012-09-19
dc.identifier.citation Wang, G. X., Zhang, H., Chen, Y., Yao, T. Y., & Fu, D. G. (1996). Studies on the magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2 (HOBz-Benzoic acid). Chinese Journal of Chemistry, 14(3), 200-205.
dc.identifier.issn 1001604X
dc.identifier.uri http://hdl.handle.net/10220/8570
dc.description.abstract The magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NP3)-(CH3OH)2 (HOBzbenzoic acid) has been studied. We use isosceles triangle model and molecular field correction to fit the experimental magnetic susceptibility data. It shows that an intramolecular antiferromagnetic exchange interaction occurs with J = -31.27 cm−1, J'= -27.26 cm−1, and a weaker intermolecular antiferromagnetic exchange interaction occurs with zJ' = - 3.76 cm−1. We give the d5-d5-d5 energy level diagram of triiron(III) complex as a function of J'/J. From the diagram we can get the total spin ST of the complex as 1/2 in the ground state.
dc.language.iso en
dc.relation.ispartofseries Chinese journal of chemistry
dc.rights © 1996 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
dc.subject DRNTU::Engineering::Materials.
dc.title Studies on the magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2 (HOBz-Benzoic acid)
dc.type Journal Article
dc.contributor.school School of Materials Science and Engineering
dc.identifier.doi http://dx.doi.org/10.1002/cjoc.19960140303

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