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https://hdl.handle.net/10356/81491
Title: | Copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines | Authors: | Tnay, Ya Lin Ang, Gim Yean Chiba, Shunsuke |
Keywords: | copper ketimines molecular oxygen radical C-C bond cleavage |
Issue Date: | 2015 | Source: | Tnay, Y. L., Ang, G. Y., & Chiba, S. (2015). Copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines. Beilstein Journal of Organic Chemistry, 11, 1933-1943. | Series/Report no.: | Beilstein Journal of Organic Chemistry | Abstract: | We report herein studies on copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines. Treatment of N-H ketimines having an alpha-sp3 hybridized carbon under Cu-catalyzed aerobic reaction conditions resulted in a radical fragmentation with C-C bond cleavage to give the corresponding carbonitrile and carbon radical intermediate. This radical process has been applied for the construction of oxaspirocyclohexadienones as well as in the electrophilic cyanation of Grignard reagents with pivalonitrile as a CN source. | URI: | https://hdl.handle.net/10356/81491 http://hdl.handle.net/10220/40822 |
ISSN: | 1860-5397 | DOI: | 10.3762/bjoc.11.209 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2015 The Author(s) (Published by Beilstein-Institut). This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Journal Articles |
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Copper-catalyzed aerobic radical C-C bond cleavage of N-H ketimines.pdf | 571.7 kB | Adobe PDF | View/Open |
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