dc.contributor.authorWang, Xiao-Jun
dc.contributor.authorLi, Pei-Zhou
dc.contributor.authorChen, Yifei
dc.contributor.authorZhang, Quan
dc.contributor.authorZhang, Huacheng
dc.contributor.authorChan, Xiu Xiang
dc.contributor.authorGanguly, Rakesh
dc.contributor.authorLi, Yongxin
dc.contributor.authorJiang, Jianwen
dc.contributor.authorZhao, Yanli
dc.identifier.citationWang, X. J., Li, P. Z., Chen, Y., Zhang, Q., Zhang, H., Chan, X. X., et al. (2013). A Rationally Designed Nitrogen-Rich Metal-Organic Framework and Its Exceptionally High CO2 and H2 Uptake Capability. Scientific Reports 3, 1149.en_US
dc.description.abstractOn the way towards a sustainable low-carbon future, the design and construction of chemical or physical adsorbents for CO2 capture and clean energy storage are vital technology. The incorporation of accessible nitrogen-donor sites into the pore walls of porous adsorbents can dramatically affect the CO2 uptake capacity and selectivity on account of the dipole-quadrupole interactions between the polarizable CO2 molecule and the accessible nitrogen site. In the present work, a nitrogen-rich rth-type metal-organic framework (MOF) was constructed based on rational design and careful synthesis. The MOF presents exceptionally high uptake capacity not only for CO2 but also for H2, which is attributed to favorable interactions between the gas molecules and the nitrogen-rich triazole units of the MOF proved by both experimental measurements and theoretical molecular simulations.en_US
dc.relation.ispartofseriesScientific reportsen_US
dc.rights© 2013 The Author(s). This paper was published in Scientific Reports and is made available as an electronic reprint (preprint) with permission of The Author(s). The paper can be found at the following official DOI: [http://dx.doi.org/10.1038/srep01149]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.en_US
dc.subjectDRNTU::Science::Chemistry::Analytical chemistry::Gas analysis
dc.titleA rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capabilityen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.description.versionPublished versionen_US

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