Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/96109
Title: A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2 and H2 uptake capability
Authors: Wang, Xiao-Jun
Li, Pei-Zhou
Chen, Yifei
Zhang, Quan
Zhang, Huacheng
Chan, Xiu Xiang
Ganguly, Rakesh
Li, Yongxin
Jiang, Jianwen
Zhao, Yanli
Keywords: DRNTU::Science::Chemistry::Analytical chemistry::Gas analysis
Issue Date: 2013
Source: Wang, X. J., Li, P. Z., Chen, Y., Zhang, Q., Zhang, H., Chan, X. X., et al. (2013). A Rationally Designed Nitrogen-Rich Metal-Organic Framework and Its Exceptionally High CO2 and H2 Uptake Capability. Scientific Reports 3, 1149.
Series/Report no.: Scientific reports
Abstract: On the way towards a sustainable low-carbon future, the design and construction of chemical or physical adsorbents for CO2 capture and clean energy storage are vital technology. The incorporation of accessible nitrogen-donor sites into the pore walls of porous adsorbents can dramatically affect the CO2 uptake capacity and selectivity on account of the dipole-quadrupole interactions between the polarizable CO2 molecule and the accessible nitrogen site. In the present work, a nitrogen-rich rth-type metal-organic framework (MOF) was constructed based on rational design and careful synthesis. The MOF presents exceptionally high uptake capacity not only for CO2 but also for H2, which is attributed to favorable interactions between the gas molecules and the nitrogen-rich triazole units of the MOF proved by both experimental measurements and theoretical molecular simulations.
URI: https://hdl.handle.net/10356/96109
http://hdl.handle.net/10220/10003
DOI: http://dx.doi.org/10.1038/srep01149
Rights: © 2013 The Author(s). This paper was published in Scientific Reports and is made available as an electronic reprint (preprint) with permission of The Author(s). The paper can be found at the following official DOI: [http://dx.doi.org/10.1038/srep01149]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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