dc.contributor.authorXu, Chang.
dc.contributor.authorLow, Wei Chuan.
dc.contributor.authorLi, Yongxin.
dc.contributor.authorPullarkat, Sumod A.
dc.date.accessioned2013-06-13T03:26:52Z
dc.date.available2013-06-13T03:26:52Z
dc.date.copyright2012en_US
dc.date.issued2012
dc.identifier.citationXu, C., Low, W. C., Li, Y., & Pullarkat, S. A. (2012). One-pot β-alkylation of secondary alcohols with primary alcohols catalyzed by ruthenacycles. Tetrahedron Letters, 53(12), 1450-1455.en_US
dc.identifier.issn0040-4039en_US
dc.identifier.urihttp://hdl.handle.net/10220/10309
dc.description.abstractA ruthenacycle-catalyzed one-pot β-alkylation of secondary alcohols with primary alcohols is described. A survey of four C–N chelate ruthenacycles synthesized via the cyclometallation reaction of phenylmethanamine, N-methylphenylmethanamine, N,N-dimethylphenylmethanamine, and naphthalen-1-ylmethanamine with [(η6-C6H6)RuCl2]2 was undertaken. All four complexes were found to be active with the phenylmethanamine-based ruthenacycle showing the best combination of reactivity and product selectivity among the four. An expanded scope of substrates was also studied with the inclusion of unsaturated primary alcohols. The reactivity trend observed gave insights into the role of hydrogen bonding in the catalytic mechanism involving transfer hydrogenation between the substrates and the transition metal catalyst.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesTetrahedron lettersen_US
dc.rights© 2012 Elsevier Ltd.en_US
dc.titleOne-pot β-alkylation of secondary alcohols with primary alcohols catalyzed by ruthenacyclesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1016/j.tetlet.2012.01.025


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