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Title: N-heterocyclic carbene catalyzed C-glycosylation : a concise approach from Stetter reaction
Authors: Vedachalam, Seenuvasan
Tan, Shi Min
Teo, Hui Ping
Cai, Shuting
Liu, Xue-Wei
Issue Date: 2011
Source: Vedachalam, S., Tan, S. M., Teo, H. P., Cai, S., & Liu, X.-W. (2012). N-Heterocyclic Carbene Catalyzed C-Glycosylation: A Concise Approach from Stetter Reaction. Organic Letters, 14(1), 174-177.
Series/Report no.: Organic letters
Abstract: Described herein is the first example of an organocatalytic approach for acylanion addition to the anomeric carbon of 2-nitroglucal using an N-heterocyclic carbene catalyst. Control over the reaction conditions gives β-selective and nitro-eliminated C-glycosides, providing opportunities to produce new classes of C-glycoside.
ISSN: 1523-7060
DOI: 10.1021/ol202959y
Rights: © 2011 American Chemical Society.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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