dc.contributor.authorPapper, Vladislav
dc.contributor.authorGorgy, Karine
dc.contributor.authorElouarzaki, Kamal
dc.contributor.authorSukharaharja, Ayrine
dc.contributor.authorCosnier, Serge
dc.contributor.authorMarks, Robert S.
dc.date.accessioned2013-07-02T02:45:21Z
dc.date.available2013-07-02T02:45:21Z
dc.date.copyright2013en_US
dc.date.issued2013
dc.identifier.citationPapper, V., Gorgy, K., Elouarzaki, K., Sukharaharja, A., Cosnier, S,. & Marks, R. S.(2013). Biofunctionalization of multiwalled carbon nanotubes by irradiation of electropolymerized poly(pyrrole-diazirine) films. Chemistry - A European Journal, 19(29), 9639-9643.en_US
dc.identifier.issn1521-3765en_US
dc.identifier.urihttp://hdl.handle.net/10220/10875
dc.description.abstractA photoactivatable poly(pyrrole–diazirine) film was synthesized and electropolymerized as a versatile tool for covalent binding of laccase and glucose oxidase on multiwalled carbon nanotube coatings and Pt, respectively. Irradiation of the functionalized nanotubes allowed photochemical grafting of laccase and its subsequent direct electrical wiring, as illustrated by the electrocatalytic reduction of oxygen. Moreover, covalent binding of glucose oxidase as model enzyme, achieved by UV activation of electropolymerized pyrrole–diazirine, allowed a glucose biosensor to be realized. This original method to graft biomolecules combines electrochemical and photochemical techniques. The simplicity of this new method allows it to be extended easily to other biological systems.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemistry - a European journalen_US
dc.rights© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.titleBiofunctionalization of multiwalled carbon nanotubes by irradiation of electropolymerized poly(pyrrole-diazirine) filmsen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doihttp://dx.doi.org/10.1002/chem.201300873
dc.identifier.rims171955


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