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      Non-aqueous energy storage devices using graphene nanosheets synthesized by green route

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      13. Non-aqueous energy storage devices using graphene nanosheets.pdf (1.578Mb)
      Author
      Mhamane, Dattakumar
      Suryawanshi, Anil
      Banerjee, Abhik
      Aravindan, Vanchiappan
      Ogale, Satishchandra
      Srinivasan, Madhavi
      Date of Issue
      2013
      School
      School of Materials Science and Engineering
      Research Centre
      Energy Research Institute
      Version
      Published version
      Abstract
      In this paper we report the use of triethylene glycol reduced graphene oxide (TRGO) as an electrode material for non-aqueous energy storage devices such as supercapacitors and Li-ion batteries. TRGO based non–aqueous symmetric supercapacitor is constructed and shown to deliver maximum energy and power densities of 60.4 Wh kg–1 and 0.15 kW kg–1, respectively. More importantly, symmetric supercapacitor shows an extraordinary cycleability (5000 cycles) with over 80% of capacitance retention. In addition, Li-storage properties of TRGO are also evaluated in half-cell configuration (Li/TRGO) and shown to deliver a reversible capacity of ∼705 mAh g–1 with good cycleability at constant current density of 37 mA g–1. This result clearly suggests that green-synthesized graphene can be effectively used as a prospective electrode material for non-aqueous energy storage systems such as Li-ion batteries and supercapacitors.
      Type
      Journal Article
      Series/Journal Title
      AIP advances
      Rights
      © 2013 The Authors. This paper was published in AIP Advances and is made available as an electronic reprint (preprint) with permission of The Authors. The paper can be found at the following official DOI: [http://dx.doi.org/10.1063/1.4802243]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.
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      http://dx.doi.org/10.1063/1.4802243
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