Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles
Author
Qi, Xinxin
Xu, Xianxiu
Park, Cheol-Min
Date of Issue
2012School
School of Physical and Mathematical Sciences
Abstract
Free carbenes generated from α-diazo oxime ethers by photolysis undergo facile N–O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition.
Type
Journal Article
Series/Journal Title
Chemical communications
Rights
© 2012 The Royal Society of Chemistry.
Collections
http://dx.doi.org/10.1039/c2cc30490b
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