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      Facile synthesis of 2-alkyl/aryloxy-2H-azirines and their application in the synthesis of pyrroles

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      Author
      Qi, Xinxin
      Xu, Xianxiu
      Park, Cheol-Min
      Date of Issue
      2012
      School
      School of Physical and Mathematical Sciences
      Abstract
      Free carbenes generated from α-diazo oxime ethers by photolysis undergo facile N–O insertion to afford 2-alkyl/aryloxy-2H-azirines in good to excellent yields. This method allowed for the development of a tandem reaction for pyrrole synthesis via 1,3-dipolar cycloaddition.
      Type
      Journal Article
      Series/Journal Title
      Chemical communications
      Rights
      © 2012 The Royal Society of Chemistry.
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      • SPMS Journal Articles
      http://dx.doi.org/10.1039/c2cc30490b
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