Approaching a stable, green twisted heteroacene through “clean reaction” strategy
Author
Li, Gang
Duong, Hieu M.
Zhang, Zhonghan
Xiao, Jinchong
Liu, Lei
Zhao, Yanli
Zhang, Hua
Huo, Fengwei
Li, Shuzhou
Ma, Jan
Wudl, Fred
Zhang, Qichun
Date of Issue
2012School
School of Materials Science and Engineering
School of Physical and Mathematical Sciences
School of Physical and Mathematical Sciences
Abstract
A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a “clean reaction” strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO–LUMO bandgap is in good agreement with experimental data.
Type
Journal Article
Series/Journal Title
Chemical communications
Rights
© 2012 The Royal Society of Chemistry.
Collections
http://dx.doi.org/10.1039/c2cc32048g
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