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      Approaching a stable, green twisted heteroacene through “clean reaction” strategy

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      Author
      Li, Gang
      Duong, Hieu M.
      Zhang, Zhonghan
      Xiao, Jinchong
      Liu, Lei
      Zhao, Yanli
      Zhang, Hua
      Huo, Fengwei
      Li, Shuzhou
      Ma, Jan
      Wudl, Fred
      Zhang, Qichun
      Date of Issue
      2012
      School
      School of Materials Science and Engineering
      School of Physical and Mathematical Sciences
      Abstract
      A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a “clean reaction” strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO–LUMO bandgap is in good agreement with experimental data.
      Type
      Journal Article
      Series/Journal Title
      Chemical communications
      Rights
      © 2012 The Royal Society of Chemistry.
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      • MSE Journal Articles
      http://dx.doi.org/10.1039/c2cc32048g
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