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|Title:||Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework||Authors:||Rakesh, Ganguly
Wong, Jinye Daniel
Chan, Xiu Xiang
|Issue Date:||2012||Source:||Wang, X.-J., Li, P.-Z., Liu, L., Zhang, Q., Borah, P., Wong, J. D., et al. (2012). Significant gas uptake enhancement by post-exchange of zinc(II) with copper(II) within a metal–organic framework. Chemical Communications, 48(83), 10268-10288.||Series/Report no.:||Chemical communications||Abstract:||Coordination of a tetratopic nitrogen-rich linker with Zn2+ under solvothermal conditions afforded a Zn-based metal organic framework (MOF), where the Zn(II) ions could be exchanged by Cu(II) ions in a single-crystal-to-single-crystal fashion leading to a new Cu-based MOF. Such transformation induces a significant enhancement in gas sorption along with a high selectivity towards CO2 over N2 and CH4.||URI:||https://hdl.handle.net/10356/101388
|DOI:||10.1039/c2cc34921c||Rights:||© 2012 The Royal Society of Chemistry.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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