Suzuki–Miyaura cross-coupling reaction catalyzed by PEPPSI-type 1,4-Di(2,6-diisopropylphenyl)-1,2,3-triazol-5-ylidene (tzIPr) palladium complex
Hong, Soon Hyeok
Date of Issue2012
School of Physical and Mathematical Sciences
A 1,4-di(2,6-diisopropylphenyl)-1,2,3-triazol-5-ylidene (tzIPr)-based PEPPSI-type palladium complex was developed as an excellent precatalyst for the Suzuki–Miyaura cross-coupling reaction. The complex showed high activity under mild conditions for the cross-coupling reactions between various types of aryl chlorides and aryl boronic acids regardless of the steric and electronic nature of the substrates.
European journal of organic chemistry
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