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Title: Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate : structural diversity and properties
Authors: Zheng, Sheng-Run
Tan, Jing-Bo
Zhang, Wei-Guang
Wang, Ning
Cai, Song-Liang
Yin, Xia
Xiao, Tian-Tian
Fan, Jun
Issue Date: 2012
Source: Yin, X., Xiao, T.-T., Fan, J., Zheng, S.-R., Wang, N., Cai, S.-L., et al. (2012). Assembly of two new Mn(II) coordination polymers based on 5-aminoisophthalate: Structural diversity and properties. Inorganic Chemistry Communications, 22, 93-97.
Series/Report no.: Inorganic chemistry communications
Abstract: Two new Mn(II) coordination polymers, namely, [Mn(Haip)2(H2O)2] (1), and [Mn2(aip)2(bpy)]·3H2O (2) were obtained under hydrothermal conditions (aip = 5-aminoisophthalate; bpy = 2, 2′-bipyridine). Compound 1 features a 1D loop-like chain structure, and complex 2 possesses an interesting (3, 5)-connected 2-nodal 3D architecture with the Schläfli symbol of (4.62)(4.67.82), which is constructed from helical chains. Coordination modes of H2aip molecules and coligands have significant effect on the structures of the resulting complexes. Moreover, variable-temperature magnetic susceptibility measurement of complex 2 exhibits antiferromagnetic interactions between nearest Mn(II) ions with J = − 0.88(5) cm− 1 and g = 2.04(3).
ISSN: 1387-7003
DOI: 10.1016/j.inoche.2012.05.031
Rights: © 2012 Elsevier B.V.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles

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