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https://hdl.handle.net/10356/98400
Title: | Palladium-catalyzed direct C-H arylation of enamides with simple arenes | Authors: | Pankajakshan, Sreekumar Xu, Yun-He Cheng, Jun Kee Low, Man Ting Loh, Teck-Peng |
Keywords: | DRNTU::Science::Chemistry | Issue Date: | 2012 | Source: | Pankajakshan, S., Xu, Y.-H., Cheng, J. K., Low, M. T., & Loh, T.-P. (2012). Palladium-Catalyzed Direct C-H Arylation of Enamides with Simple Arenes. Angewandte Chemie International Edition, 51(23), 5701-5705. | Series/Report no.: | Angewandte chemie international edition | Abstract: | Z only: An atom-economical synthetic route towards arylated Z-enamides through double CH functionalization is described. The Z/E selectivity of the palladium-catalyzed monoarylation is absolute (step A in scheme), and the molecular complexity of the products can be further endowed by a sequential second arylation, which requires the use of trifluoracetic acid (TFA; step B). | URI: | https://hdl.handle.net/10356/98400 http://hdl.handle.net/10220/12496 |
ISSN: | 1433-7851 | DOI: | 10.1002/anie.201109247 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | SPMS Journal Articles |
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