Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/98871
Title: Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone
Authors: Xiao, Jinchong
Zhang, Qichun
Azuma, Yasuo
Liu, Yi
Li, Gang
Wei, Fengxia
Majima, Yutaka
Tan, Ke Jie
Zhang, Hua
Kloc, Christian
Issue Date: 2012
Source: Xiao, J., Azuma, Y., Liu, Y., Li, G., Wei, F., Tan, K. J., Kloc, C., Zhang, H., Majima, Y., & Zhang, Q. (2012). Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone. Australian journal of chemistry, 65(12), 1674-1678.
Series/Report no.: Australian journal of chemistry
Abstract: An n-type organic semiconductor 2:3,5:6-bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone (BDQ) has been successfully synthesised and characterised. The single crystal structure of BDQ, determined by single-crystal X-ray crystallography, indicated that BDQ is a planar molecule with strong face-to-face π-π stacking (3.40 Å) and S···S interactions (3.66 Å) between neighbouring molecules, which might be in favour of the effective charge transport. The UV-vis spectrum shows that BDQ has shoulder absorption up to 550 nm (2.25 eV). The electrochemical property displays that the HOMO-LUMO gap of BDQ obtained from the half-wave redox potential is 1.92 eV. The displacement current measurement of BDQ-based devices is demonstrated and discussed.
URI: https://hdl.handle.net/10356/98871
http://hdl.handle.net/10220/12648
ISSN: 0004-9425
DOI: http://dx.doi.org/10.1071/CH12325
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:MSE Journal Articles

Google ScholarTM

Check

Altmetric

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.