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|Title:||Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone||Authors:||Xiao, Jinchong
Tan, Ke Jie
|Issue Date:||2012||Source:||Xiao, J., Azuma, Y., Liu, Y., Li, G., Wei, F., Tan, K. J., Kloc, C., Zhang, H., Majima, Y., & Zhang, Q. (2012). Synthesis, structure, physical properties, and displacement current measurement of an n-type organic semiconductor: 2:3,5:6-Bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone. Australian journal of chemistry, 65(12), 1674-1678.||Series/Report no.:||Australian journal of chemistry||Abstract:||An n-type organic semiconductor 2:3,5:6-bis(1,1-dicyanoethylene-2,2-dithiolate)-quinone (BDQ) has been successfully synthesised and characterised. The single crystal structure of BDQ, determined by single-crystal X-ray crystallography, indicated that BDQ is a planar molecule with strong face-to-face π-π stacking (3.40 Å) and S···S interactions (3.66 Å) between neighbouring molecules, which might be in favour of the effective charge transport. The UV-vis spectrum shows that BDQ has shoulder absorption up to 550 nm (2.25 eV). The electrochemical property displays that the HOMO-LUMO gap of BDQ obtained from the half-wave redox potential is 1.92 eV. The displacement current measurement of BDQ-based devices is demonstrated and discussed.||URI:||https://hdl.handle.net/10356/98871
|ISSN:||0004-9425||DOI:||http://dx.doi.org/10.1071/CH12325||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||MSE Journal Articles|
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