dc.contributor.authorXiao, Jinchong
dc.contributor.authorLiu, Shuwei
dc.contributor.authorLiu, Yi
dc.contributor.authorJi, Li
dc.contributor.authorLiu, Xue-Wei
dc.contributor.authorZhang, Hua
dc.contributor.authorSun, Xiaowei
dc.contributor.authorZhang, Qichun
dc.date.accessioned2013-08-02T07:55:30Z
dc.date.available2013-08-02T07:55:30Z
dc.date.copyright2012en_US
dc.date.issued2012
dc.identifier.citationXiao, J., Liu, S., Liu, Y., Ji, L., Liu, X., Zhang, H., Sun, X.,& Zhang, Q. (2012). Synthesis, Structure, and Physical Properties of 5,7,14,16-Tetraphenyl-8:9,12:13-bisbenzo-hexatwistacene. Chemistry - An Asian Journal, 7(3), 561-564.en_US
dc.identifier.issn1861-4728en_US
dc.identifier.urihttp://hdl.handle.net/10220/12954
dc.description.abstractA novel compound, 5,7,14,16-tetraphenyl-8:9,12:13-bisbenzo-hexatwistacene (TBH), has been successfully synthesized through a retro-Diels–Alder reaction. Single-crystal structure analysis indicated that TBH has a twisted configuration with a torsion angle of 27.34°. The HOMO–LUMO gap of TBH calculated from the difference between the half-wave redox potentials (E1/2ox=+0.40 eV and E1/2red=−1.78 eV) is 2.18 eV, which is in good agreement with the band gap (2.19 eV) derived from the UV/Vis absorption data. In addition, organic light-emitting devices using TBH as emitter have been fabricated. The results revealed that TBH is a promising red light-emitting candidate for applications in organic light-emitting diodes.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemistry - an Asian journalen_US
dc.titleSynthesis, structure, and physical properties of 5,7,14,16-Tetraphenyl-8:9,12:13-bisbenzo-hexatwistaceneen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Electrical and Electronic Engineeringen_US
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/asia.201100733


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