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      Novel assembly of an MoS2 electrocatalyst onto a silicon nanowire array electrode to construct a photocathode composed of elements abundant on the Earth for hydrogen generation

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      Author
      Tran, Phong D.
      Pramana, Stevin S.
      Kale, Vinayak S.
      Nguyen, Mai
      Chiam, Sing Yang
      Batabyal, Sudip Kumar
      Wong, Lydia Helena
      Barber, James
      Loo, Say Chye Joachim
      Date of Issue
      2012
      School
      School of Materials Science and Engineering
      Research Centre
      Energy Research Institute
      Abstract
      Mild-mannered catalyst: A novel procedure to load a MoS2 co-catalyst onto the surface of silicon under mild-conditions (room temperature, atmospheric pressure, aqueous solution) by a photo-assisted electrodeposition process employing commercially available precursors is reported. The obtained Si-NW@MoS2 photocathode showed similar catalytic activity for light-driven H2 generation compared with a Si-NW@Pt photocathode (see scheme).
      Type
      Journal Article
      Series/Journal Title
      Chemistry - a European journal
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      • MSE Journal Articles
      • ERI@N Journal Articles
      http://dx.doi.org/10.1002/chem.201202214
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