Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/100844
Title: | Role of steric strain in the chemistry of phosphiranes | Authors: | Ho, Feny Li, Yongxin Mathey, François |
Issue Date: | 2012 | Source: | Ho, F., Li, Y., & Mathey, F. (2012). Role of Steric Strain in the Chemistry of Phosphiranes. Organometallics, 31(23), 8456–8458. | Series/Report no.: | Organometallics | Abstract: | The reaction of transient [MeP-W(CO)5] with norbornene gives the two corresponding exo phosphiranes with W syn or anti to the norbornane bridge. The syn complex is selectively decomplexed by carbon monoxide at 120 °C under 50 bar. Both complexes are easily cleaved by Pd(OAc)2 at room temperature to give [MeP(OAc)2)]W(CO)5. | URI: | https://hdl.handle.net/10356/100844 http://hdl.handle.net/10220/13693 |
DOI: | 10.1021/om3007807 | Schools: | School of Physical and Mathematical Sciences | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | SPMS Journal Articles |
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