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|Title:||A new type of phosphaferrocene–pyrrole–phosphaferrocene P-N-P pincer ligand||Authors:||Tian, Rongqiang
|Keywords:||DRNTU::Science::Chemistry||Issue Date:||2012||Source:||Tian, R., Ng, Y., Ganguly, R., & Mathey, F. (2012). A new type of phosphaferrocene–pyrrole–phosphaferrocene P-N-P pincer ligand. Organometallics, 31(6), 2486-2488.||Series/Report no.:||Organometallics||Abstract:||A 2-ethoxycarbonylphosphaferrocene was reduced to the corresponding 2-hydroxymethyl derivative, which was condensed with pyrrole in a 2:1 ratio in the presence of BF3 to give a phosphaferrocene–pyrrole–phosphaferrocene pincer ligand. This tridentate ligand, in turn, reacted with [Rh(acac)(CO)2] to yield a rhodium carbonyl pincer complex. This complex was characterized by X-ray crystal structure analysis and tested in the hydroformylation of internal olefins.||URI:||https://hdl.handle.net/10356/99361
|Appears in Collections:||SPMS Journal Articles|
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