dc.contributor.authorSong, Xianghua
dc.contributor.authorWang, Yabo
dc.contributor.authorWang, Kean
dc.contributor.authorXu, Rong
dc.date.accessioned2013-10-23T05:49:21Z
dc.date.available2013-10-23T05:49:21Z
dc.date.copyright2012en_US
dc.date.issued2012
dc.identifier.citationSong, X., Wang, Y., Wang, K., & Xu, R. (2012). Low-cost carbon nanospheres for efficient removal of organic dyes from aqueous solutions. Industrial & Engineering Chemistry Research, 51(41), 13438-13444.en_US
dc.identifier.issn0888-5885en_US
dc.identifier.urihttp://hdl.handle.net/10220/16708
dc.description.abstractColloidal carbon nanospheres (CNS) with rich surface functional groups of −OH and −COO– were prepared from glucose solution via hydrothermal reaction and activated by NaOH solution. The nonporous CNS exhibited excellent adsorption performance toward basic dyes. High maximum adsorption capacities were obtained at 682 mg g–1 for Methylene blue, 395 mg g–1 for Methyl violet 2B, and 310 mg g–1 for Malachite green. Methylene blue with an initial concentration of 94 mg L–1 can be completely removed in 5 min at a dosage of 0.5 g L–1. This can be associated with the low mass transfer resistance due to the nonporous structure and the abundant surface active sites. The adsorption process is chemisorption in nature, while the kinetic data were well fitted to pseudosecond-order kinetic model. This material presented excellent adsorption capacities toward basic dyes with maximum adsorption capacity of 682 mg g–1 for Methylene blue B, 310 mg g–1 for Malachite green, and 395 mg g–1 for Methyl violet 2B. Furthermore, the dye saturated CNS was regenerated using an advanced oxidation method using Co2+ in aqueous solution as a homogeneous catalyst. After seven recycle runs, there was still 96% of adsorption capacity retained. The low-cost CNS nanomaterial has the potential to be applied as a new type of efficient adsorbent for water treatment.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesIndustrial & Engineering Chemistry Researchen_US
dc.rights© 2012 American Chemical Societyen_US
dc.subjectDRNTU::Engineering::Chemical engineering
dc.titleLow-cost carbon nanospheres for efficient removal of organic dyes from aqueous solutionsen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.identifier.doihttp://dx.doi.org/10.1021/ie300914h


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