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|Title:||Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl⋯Cl contacts of 2.524 Å inside organic crystals||Authors:||Huo, Yan-Ping
Ong, Wei Qiang
|Issue Date:||2012||Source:||Zhou, F., Fu, H., Ong, W. Q., Ye, R., Yuan, W., Lu, Y.-J., et al. (2012). Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl⋯Cl contacts of 2.524 Å inside organic crystals. Organic & Biomolecular Chemistry, 10(29), 5525-5528.||Series/Report no.:||Organic & biomolecular chemistry||Abstract:||1D helical channels can be created by “sticky” end-mediated formation of 1D helical stacks composed of short cavity-containing helices and are able to host 1D chains of dichloromethane molecules containing extraordinarily short intermolecular Cl⋯Cl contacts of 2.524 Å in length that computationally destabilize the host–guest complex by 14.94 kcal mol^−1.||URI:||https://hdl.handle.net/10356/99033
|DOI:||http://dx.doi.org/10.1039/c2ob25888a||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||MSE Journal Articles|
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