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Title: Aldimine-directed branched-selective hydroarylation of styrenes
Authors: Lee, Pin-Sheng
Yoshikai, Naohiko
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Issue Date: 2013
Source: Lee, P.-S., & Yoshikai, N. (2013). Aldimine-directed branched-selective hydroarylation of styrenes. Angewandte chemie international edition, 52(4), 1240-1244.
Series/Report no.: Angewandte chemie international edition
Abstract: Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation products is amenable to dehydrative cyclization, to give fused polycyclic aromatic hydrocarbons, as well as decarbonylative removal.
DOI: 10.1002/anie.201207958
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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