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https://hdl.handle.net/10356/98202| Title: | Aldimine-directed branched-selective hydroarylation of styrenes | Authors: | Lee, Pin-Sheng Yoshikai, Naohiko |
Keywords: | DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis | Issue Date: | 2013 | Source: | Lee, P.-S., & Yoshikai, N. (2013). Aldimine-directed branched-selective hydroarylation of styrenes. Angewandte chemie international edition, 52(4), 1240-1244. | Series/Report no.: | Angewandte chemie international edition | Abstract: | Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation products is amenable to dehydrative cyclization, to give fused polycyclic aromatic hydrocarbons, as well as decarbonylative removal. | URI: | https://hdl.handle.net/10356/98202 http://hdl.handle.net/10220/17258 |
DOI: | 10.1002/anie.201207958 | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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