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      Aldimine-directed branched-selective hydroarylation of styrenes

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      Author
      Lee, Pin-Sheng
      Yoshikai, Naohiko
      Date of Issue
      2013
      School
      School of Physical and Mathematical Sciences
      Abstract
      Branching out: A simple and inexpensive cobalt/triarylphosphine catalyst promotes aldimine-directed hydroarylation of styrene with high branched regioselectivity to afford 1,1-diarylethane derivatives in good yields under mild reaction conditions. The ortho-formyl group in the hydroarylation products is amenable to dehydrative cyclization, to give fused polycyclic aromatic hydrocarbons, as well as decarbonylative removal.
      Subject
      DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
      Type
      Journal Article
      Series/Journal Title
      Angewandte chemie international edition
      Collections
      • SPMS Journal Articles
      http://dx.doi.org/10.1002/anie.201207958
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