dc.contributor.authorZhu, Liangliang
dc.contributor.authorLi, Xin
dc.contributor.authorWu, Shaojue
dc.contributor.authorNguyen, Kim Truc
dc.contributor.authorYan, Hong
dc.contributor.authorÅgren, Hans
dc.contributor.authorZhao, Yanli
dc.date.accessioned2013-11-07T06:39:19Z
dc.date.available2013-11-07T06:39:19Z
dc.date.copyright2013en_US
dc.date.issued2013
dc.identifier.citationZhu, L., Li, X., Wu, S., Nguyen, K. T., Yan, H., Ågren, H., et al. (2013). Chirality control for in situ preparation of gold nanoparticle superstructures directed by a coordinatable organogelator. Journal of the American chemical society, 135(24), 9174-9180.en_US
dc.identifier.urihttp://hdl.handle.net/10220/17377
dc.description.abstractImposing chirality into nanoscale superstructures is a major step forward toward systematic understanding and utilization of nanomaterials. In an attempt to achieve tunable chirality during in situ preparation of hybrid nanomaterials, we here report a novel unimolecular strategy of employing a coordinatable organogelator for the realization of chirality control in the formation of gold nanoparticle superstructures. The work takes advantage of thermally reversible sol–gel transition of the chiral dispersion as template, which causes different micelle properties that can influence the coordination ability between the organogelator and Au(III) ions. Followed by a reduction reaction, gold nanoparticle superstructures with P-helicity were prepared from the sol form of the template through a coordination-induced chiral inversion, whereas those with M-helicity were obtained from the gel form with chiral holding. Such superstructures are solvent-stable and the chirality difference between them could be observed in many solvent environments.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesJournal of the American chemical societyen_US
dc.subjectDRNTU::Science::Chemistry
dc.titleChirality control for in situ preparation of gold nanoparticle superstructures directed by a coordinatable organogelatoren_US
dc.typeJournal Article
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1021/ja403722t


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