dc.contributor.authorYan, Lin
dc.contributor.authorHan, Zhiqiang
dc.contributor.authorZhu, Bo
dc.contributor.authorYang, Caiyun
dc.contributor.authorTan, Choon-Hong
dc.contributor.authorJiang, Zhiyong
dc.date.accessioned2013-11-08T02:32:46Z
dc.date.available2013-11-08T02:32:46Z
dc.date.copyright2013en_US
dc.date.issued2013
dc.identifier.citationYan, L., Han, Z., Zhu, B., Yang, C., Tan, C.-H., & Jiang, Z. (2013). Asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with α-fluoro-β-keto esters. Beilstein journal of organic chemistry, 9, 1853-1857.en_US
dc.identifier.urihttp://hdl.handle.net/10220/17425
dc.description.abstractIn the presence of a commercially available Cinchona alkaloid as catalyst, the asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates, with α-fluoro-β-keto esters as nucleophiles, have been successfully developed. A series of important fluorinated adducts, with chiral quaternary carbon centres containing a fluorine atom, was achieved in good yields (up to 93%), with good to excellent enantioselectivities (up to 96% ee) and moderate diastereoselectivities (up to 4:1 dr).en_US
dc.language.isoenen_US
dc.relation.ispartofseriesBeilstein journal of organic chemistryen_US
dc.rights© 2013 Yan et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions:(http://www.beilstein-journals.org/bjoc)
dc.subjectDRNTU::Science::Chemistry::Organic chemistry
dc.titleAsymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with α-fluoro-β-keto estersen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.3762/bjoc.9.216
dc.description.versionPublished Version


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