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      Bicyclic guanidinium-catalyzed enantioselective phase-transfer alkylation : direct access to pyrroloindolines and furoindolines

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      Author
      Chen, Wenchao
      Yang, Wenguo
      Yan, Lin
      Tan, Choon-Hong
      Jiang, Zhiyong
      Date of Issue
      2013
      School
      School of Physical and Mathematical Sciences
      Abstract
      Highly enantioselective phase-transfer alkylation of 3-substituted-2-oxindoles with activated bromomethanes is disclosed with a broad substrate scope by using bicyclic guanidinium as a catalyst and a Lewis acid as the co-catalyst. The alkylation adducts are versatile intermediates to accomplish the syntheses of pyrroloindolines and furoindolines.
      Subject
      DRNTU::Science::Chemistry
      Type
      Journal Article
      Series/Journal Title
      Chemical communications
      Collections
      • SPMS Journal Articles
      http://dx.doi.org/10.1039/c3cc46111d
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