Please use this identifier to cite or link to this item:
Title: cis-Enals in N-heterocyclic carbene-catalyzed reactions : distinct stereoselectivity and reactivity
Authors: Chen, Xingkuan
Fang, Xinqiang
Chi, Robin Yonggui
Keywords: Physical and Mathematical Sciences
Issue Date: 2013
Source: Chen, X., Fang, X., & Chi, Y. R. (2013). cis-Enals in N-heterocyclic carbene-catalyzed reactions: distinct stereoselectivity and reactivity. Chemical Science, 4(6), 2613-2618.
Series/Report no.: Chemical science
Abstract: The first successful generation of cis-homoenolate equivalents from cis-enals under the catalysis of N-heterocyclic carbenes (NHCs) has been realized. The cis-homoenolate intermediates undergo effective reactions with α,β-unsaturated imines to afford chiral cyclic ketone products. Compared to the trans-enals, cis-enals show different stereoselectivities and new reactivity patterns.
DOI: 10.1039/c3sc50666e
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

Google ScholarTM




Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.