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|Title:||cis-Enals in N-heterocyclic carbene-catalyzed reactions : distinct stereoselectivity and reactivity||Authors:||Chen, Xingkuan
Chi, Robin Yonggui
|Keywords:||Physical and Mathematical Sciences||Issue Date:||2013||Source:||Chen, X., Fang, X., & Chi, Y. R. (2013). cis-Enals in N-heterocyclic carbene-catalyzed reactions: distinct stereoselectivity and reactivity. Chemical Science, 4(6), 2613-2618.||Series/Report no.:||Chemical science||Abstract:||The first successful generation of cis-homoenolate equivalents from cis-enals under the catalysis of N-heterocyclic carbenes (NHCs) has been realized. The cis-homoenolate intermediates undergo effective reactions with α,β-unsaturated imines to afford chiral cyclic ketone products. Compared to the trans-enals, cis-enals show different stereoselectivities and new reactivity patterns.||URI:||https://hdl.handle.net/10356/99694
|DOI:||10.1039/c3sc50666e||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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