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|Title:||Synthesis, structural characterisation and stereochemical investigation of chiral sulfur-functionalised N-heterocyclic carbene complexes of palladium and platinum||Authors:||Krishnan, Deepa
Pullarkat, Sumod A.
|Keywords:||Chemistry and Biological Chemistry||Issue Date:||2013||Source:||Krishnan, D., Pullarkat, S. A., Wu, M., Li, Y., & Leung, P.-H. (2013). Synthesis, Structural Characterisation and Stereochemical Investigation of Chiral Sulfur-Functionalised N-Heterocyclic Carbene Complexes of Palladium and Platinum. Chemistry - A European Journal, 19(17), 5468-5475.||Series/Report no.:||Chemistry - a European journal||Abstract:||Palladium and platinum complexes containing a sulfur-functionalised N-heterocyclic carbene (S-NHC) chelate ligand have been synthesised. The absolute conformations of these novel organometallic S-NHC chelates were determined by X-ray structural analyses and solution-phase 2D 1H–1H ROESY NMR spectroscopy. The structural studies revealed that the phenyl substituents on the stereogenic carbon atoms invariably take up the axial positions on the Pd-C-S coordination plane to afford a skewed five-membered ring structure. All of the chiral complexes are structurally rigid and stereochemically locked in a chiral ring conformation that is either (Rs,S,R)-λ or (Ss,R,R)-δ in both the solid state and solution.||URI:||https://hdl.handle.net/10356/99806
|ISSN:||0947-6539||DOI:||http://dx.doi.org/10.1002/chem.201204320||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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