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Title: Arene CH=O hydrogen bonding : a stereocontrolling tool in palladium-catalyzed arylation and vinylation of ketones
Authors: Huang, Zhiyan
Lim, Li Hui
Chen, Zuliang
Li, Yongxin
Zhou, Feng
Su, Haibin
Zhou, Jianrong Steve
Issue Date: 2013
Series/Report no.: Angewandte chemie international edition
Abstract: Weak is powerful: For the arylation of tin enolates, the palladium catalyst engages in weak CH=O hydrogen bonds to control stereoselectivity (see scheme). Similar catalysts capable of NH=O hydrogen bonding also works well.
ISSN: 1433-7851
DOI: 10.1002/anie.201300621
Rights: © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Fulltext Permission: none
Fulltext Availability: No Fulltext
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