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|Title:||Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins||Authors:||Wu, Xiaojin
Zhou, Jianrong Steve
|Keywords:||DRNTU::Science::Chemistry||Issue Date:||2013||Source:||Wu, X., Lu, Y., Hirao, H., & Zhou, J. S. (2013). Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins. Chemistry - A European journal, 19(19), 6014-6020.||Series/Report no.:||Chemistry - a European journal||Abstract:||In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium–hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions.||URI:||https://hdl.handle.net/10356/100544
|ISSN:||0947-6539||DOI:||http://dx.doi.org/10.1002/chem.201204427||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||SPMS Journal Articles|
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