Please use this identifier to cite or link to this item:
https://hdl.handle.net/10356/100544
Title: | Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins | Authors: | Wu, Xiaojin Lu, Yunpeng Hirao, Hajime Zhou, Jianrong Steve |
Keywords: | DRNTU::Science::Chemistry | Issue Date: | 2013 | Source: | Wu, X., Lu, Y., Hirao, H., & Zhou, J. S. (2013). Achieving vinylic selectivity in Mizoroki-Heck reaction of cyclic olefins. Chemistry - A European journal, 19(19), 6014-6020. | Series/Report no.: | Chemistry - a European journal | Abstract: | In Heck reactions of cyclic olefins, the products usually have aryl groups that end up at the allylic and/or homoallylic position. We herein report new selectivity that adds aryl groups to the vinylic position. Cyclic olefins of various ring size worked well. The desired isomers were produced by palladium–hydride-catalyzed isomerization of the initial products. Thus, a specific catalyst must be used so that it can perform two jobs under one set of reaction conditions. | URI: | https://hdl.handle.net/10356/100544 http://hdl.handle.net/10220/17996 |
ISSN: | 0947-6539 | DOI: | 10.1002/chem.201204427 | Schools: | School of Physical and Mathematical Sciences | Fulltext Permission: | none | Fulltext Availability: | No Fulltext |
Appears in Collections: | SPMS Journal Articles |
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