Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/100342
Title: Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications
Authors: Baikie, Tom
Fang, Yanan
Kadro, Jeannette M.
Schreyer, Martin K.
Wei, Fengxia
Mhaisalkar, Subodh Gautam
Graetzel, Michael
White, Timothy John
Keywords: DRNTU::Engineering::Materials
Issue Date: 2013
Source: Baikie, T., Fang, Y., Kadro, J. M., Schreyer, M. K., Wei, F., Mhaisalkar, S. G., Graetzel, M.,& White, T. J. (2013). Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications. Journal of materials chemistry A, 1(18), 5628- 5641.
Series/Report no.: Journal of materials chemistry A
Abstract: The hybrid organic–inorganic perovskite (CH3NH3)PbI3 may find application in next generation solid-state sensitised solar cells. Although this material and related perovskites were discovered many decades ago, questions remain concerning their diverse structural chemistry and unusual properties. The article presents a review of previous work and provides a detailed description of the preparation, structural characterisation and physical characteristics of (CH3NH3)PbI3. The phase changes exhibited by (CH3NH3)PbI3 have been probed using variable temperature powder and single crystal X-ray diffraction, combined with differential scanning calorimetry, thermogravimetric analysis and phase contrast transmission electron microscopy. The optical band gap for (CH3NH3)PbI3 determined by UV-Visible spectroscopy was compared to values obtained from density-of-state simulation of the electronic band structure.
URI: https://hdl.handle.net/10356/100342
http://hdl.handle.net/10220/18178
DOI: http://dx.doi.org/10.1039/c3ta10518k
Rights: © 2013 Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Materials Chemistry A , Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: http://dx.doi.org/10.1039/c3ta10518k.
metadata.item.grantfulltext: open
metadata.item.fulltext: With Fulltext
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