Iridafurans from the reaction of [Cp*IrCl2]2 with carbonyl conjugated terminal alkynes : dependence of product on polarity of reaction medium
Wong, Kai Ning
Mak, Garvin Kar Hang
Fan, Wai Yip
Sridevi, Venugopal Shanmugham
Leong, Weng Kee
Date of Issue2013
School of Physical and Mathematical Sciences
Reaction of the dimeric species [Cp*IrCl2]2 with terminal alkynes containing a conjugated carbonyl group results in C–C bond formation between two or three alkyne molecules, depending on the polarity of the reaction medium. The reaction pathway has been studied experimentally and computationally.
Chemistry and Biological Chemistry
Journal of organometallic chemistry
© 2013 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Organometallic Chemistry, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.jorganchem.2013.05.021].