dc.contributor.authorKumaran, Elumalai
dc.contributor.authorLeong, Weng Kee
dc.date.accessioned2014-01-20T02:34:47Z
dc.date.available2014-01-20T02:34:47Z
dc.date.copyright2012en_US
dc.date.issued2012
dc.identifier.citationKumaran, E., & Leong, W. K. (2012). The reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexes. Organometallics, 31(13), 4849-4853.en_US
dc.identifier.urihttp://hdl.handle.net/10220/18615
dc.description.abstractThe reaction of [Cp*RhCl2]2 with an aniline (R′NH2) and a terminal alkyne (RCCH) afforded the N-containing cyclometalated rhodium complexes Cp*Rh(Cl)[N(R′)=C(CH2R)-CH=CR] via a hydroamination and a 1,2-insertion of an alkyne. A reaction pathway has been proposed on the basis of deuterium labeling experiments and computational studies.en_US
dc.description.sponsorshipMOE (Min. of Education, S’pore)en_US
dc.format.extent5p.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesOrganometallicsen_US
dc.rights© 2012 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organometallics, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/om300387q].en_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
dc.titleThe reaction of [Cp*RhCl2]2, aniline, and a terminal alkyne : formation of cyclometalated rhodium(III) complexesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1021/om300387q
dc.description.versionAccepted versionen_US


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