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|Title:||Near-infrared responsive conjugated polymers to 1.5 μm and beyond : synthesis and electrochromic switching application||Authors:||Tang, Tao
|Keywords:||Materials Science and Engineering||Issue Date:||2013||Source:||Tang, T., Ding, G., Lin, T., Chi, H., Liu, C., Lu, X., et al. (2013). Near-Infrared Responsive Conjugated Polymers to 1.5 μm and Beyond: Synthesis and Electrochromic Switching Application. Macromolecular Rapid Communications, 34(5), 431-436.||Series/Report no.:||Macromolecular rapid communications||Abstract:||Azulene-containing conjugated polymers with near-infrared absorption up to 1.5 μm and beyond are achieved by treating with trifluoroacetic acid (TFA). Density functional theory calculations reveal that the near-infrared absorption arises from a strong intramolecular charge transfer transition on the polymer backbone, and the near-infrared absorption can be tuned by the degree of protonation. Furthermore, TFA treated polymers show a ten-fold enhancement in electrochromic contrast and significantly improved switching stability, suggesting that these polymers are promising candidates for fabrication of the first generation organic near-infrared devices.||URI:||https://hdl.handle.net/10356/102559
|ISSN:||1022-1336||DOI:||http://dx.doi.org/10.1002/marc.201200695||Rights:||© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||MSE Journal Articles|
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