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|Title:||Poly(ethylene terephthalate)/clay nanocomposites with trisilanolphenyl polyhedral oligomeric silsesquioxane as dispersant : simultaneously enhanced reinforcing and stabilizing effects||Authors:||Toh, Cher Ling
Pramoda, Kumari Pallathadka
Lau, Soo Khim
|Keywords:||DRNTU::Engineering::Materials::Ceramic materials||Issue Date:||2013||Source:||Toh, C. L., Yang, L., Pramoda, K. P., Lau, S. K., & Lu, X. (2013). Poly(ethylene terephthalate)/clay nanocomposites with trisilanolphenyl polyhedral oligomeric silsesquioxane as dispersant: simultaneously enhanced reinforcing and stabilizing effects. Polymer International, 62(10), 1492-1499.||Series/Report no.:||Polymer international||Abstract:||This paper presents a new approach for the preparation of poly(ethylene terephthalate) (PET)/clay nanocomposites using surfactant-free clay (sodium montmorillonite, Na-MMT) with trisilanolphenyl polyhedral oligomeric silsesquioxane (Tsp-POSS) as dispersant. The dispersion of clay in the PET/Na-MMT/Tsp-POSS nanocomposites is enhanced over that in PET/Na-MMT by using a very small amount of Tsp-POSS, which acts as functional spacer to keep clay platelets apart and pull monomers in, and, at the same time, acts as a PET chain extender. As a result, thermomechanical properties and thermo-oxidative stability of PET/Na-MMT/Tsp-POSS are improved simultaneously compared with those of PET/organoclay nanocomposites.||URI:||https://hdl.handle.net/10356/102608
|ISSN:||0959-8103||DOI:||http://dx.doi.org/10.1002/pi.4448||Rights:||© 2013 Society of Chemical Industry.||Fulltext Permission:||none||Fulltext Availability:||No Fulltext|
|Appears in Collections:||MSE Journal Articles|
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