Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/102577
Title: Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation : formal synthesis of aspergillide A
Authors: Xiang, Shaohua
Cai, Shuting
Liu, Xue-Wei
Zeng, Jing
Ma, Jimei
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Issue Date: 2013
Source: Zeng, J., Ma, J., Xiang, S., Cai, S., & Liu, X.-W. (2013). Stereoselective β-C-glycosylation by a palladium-catalyzed decarboxylative allylation : formal synthesis of aspergillide A. Angewandte Chemie International Edition, 52(19), 5134-5137.
Series/Report no.: Angewandte chemie international edition
Abstract: Mild and sweet: The title reaction proceeds under mild conditions with high regio- and diastereoselectivity (see scheme, PG=protecting group, DiPPF=1,1′-bis(diisopropylphosphino)ferrocene). This reaction is suitable for a wide range of glycal-derived γ-ketone esters and affords C-glycosides with exclusive β-selectivity. The method was further applied to a concise formal synthesis of aspergillide A.
URI: https://hdl.handle.net/10356/102577
http://hdl.handle.net/10220/19122
ISSN: 1433-7851
DOI: http://dx.doi.org/10.1002/anie.201210266
Rights: © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
metadata.item.grantfulltext: none
metadata.item.fulltext: No Fulltext
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