dc.contributor.authorChong, Che Chang
dc.contributor.authorHirao, Hajime
dc.contributor.authorKinjo, Rei
dc.date.accessioned2014-04-07T02:56:08Z
dc.date.available2014-04-07T02:56:08Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationChong, C. C., Hirao, H., & Kinjo, R. (2014). A Concerted Transfer Hydrogenolysis: 1,3,2-Diazaphospholene-Catalyzed Hydrogenation of NN Bond with Ammonia-Borane. Angewandte Chemie International Edition, 53(13), 3342-3346.en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10220/19141
dc.description.abstract1,3,2-diazaphospholenes catalyze metal-free transfer hydrogenation of a N=N double bond using ammonia–borane under mild reaction conditions, thus allowing access to various hydrazine derivatives. Kinetic and computational studies revealed that the rate-determining step involves simultaneous breakage of the B-H and N-H bonds of ammonia–borane. The reaction is therefore viewed as a concerted type of hydrogenolysis.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAngewandte chemie international editionen_US
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry
dc.titleA concerted transfer hydrogenolysis : 1,3,2-diazaphospholene-catalyzed hydrogenation of N=N bond with ammonia-boraneen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201400099


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