dc.contributor.authorXu, Xiangya
dc.contributor.authorPooi, Benjamin
dc.contributor.authorHirao, Hajime
dc.contributor.authorHong, Soon Hyeok
dc.date.accessioned2014-04-07T04:52:27Z
dc.date.available2014-04-07T04:52:27Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationXu, X., Pooi, B., Hirao, H., & Hong, S. H. (2014). CH-π and CF-π Interactions Lead to Structural Changes of N-Heterocyclic Carbene Palladium Complexes. Angewandte Chemie International Edition, 53(5), 1283-1287.en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10220/19149
dc.description.abstractThe role of CH–π and CF–π interactions in determining the structure of N-heterocyclic carbene (NHC) palladium complexes were studied using 1H NMR spectroscopy, X-ray crystallography, and DFT calculations. The CH–π interactions led to the formation of the cis-anti isomers in 1-aryl-3-isopropylimidazol-2-ylidene-based [(NHC)2PdX2] complexes, while CF–π interactions led to the exclusive formation of the cis-syn isomer of diiodobis(3-isopropyl-1-pentafluorophenylimidazol-2-ylidene) palladium(II).en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAngewandte chemie international editionen_US
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry
dc.titleCH-π and CF-π interactions lead to structural changes of N-heterocyclic carbene palladium complexesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201309371


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