Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
Date of Issue
2013School
School of Physical and Mathematical Sciences
Version
Published version
Abstract
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
Subject
DRNTU::Science::Chemistry::Organic chemistry
Type
Journal Article
Series/Journal Title
Beilstein journal of organic chemistry
Rights
© 2013 Too et al; licensee Beilstein-Institut.
This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Collections
http://dx.doi.org/10.3762/bjoc.9.138
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