Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
Author
Too, Pei Chui
Tnay, Ya Lin
Chiba, Shunsuke
Date of Issue
2013School
School of Physical and Mathematical Sciences
Version
Published version
Abstract
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
Subject
DRNTU::Science::Chemistry::Organic chemistry
Type
Journal Article
Series/Journal Title
Beilstein journal of organic chemistry
Rights
© 2013 Too et al; licensee Beilstein-Institut.
This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Collections
http://dx.doi.org/10.3762/bjoc.9.138
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