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      Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides

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      Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides.pdf (596.0Kb)
      Author
      Too, Pei Chui
      Tnay, Ya Lin
      Chiba, Shunsuke
      Date of Issue
      2013
      School
      School of Physical and Mathematical Sciences
      Version
      Published version
      Abstract
      We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
      Subject
      DRNTU::Science::Chemistry::Organic chemistry
      Type
      Journal Article
      Series/Journal Title
      Beilstein journal of organic chemistry
      Rights
      © 2013 Too et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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      http://dx.doi.org/10.3762/bjoc.9.138
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