Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
Too, Pei Chui
Tnay, Ya Lin
Date of Issue2013
School of Physical and Mathematical Sciences
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C–H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
Beilstein journal of organic chemistry
© 2013 Too et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.