dc.contributor.authorPeng, Xingao
dc.contributor.authorTong, Benny Meng Kiat
dc.contributor.authorHirao, Hajime
dc.contributor.authorChiba, Shunsuke
dc.date.accessioned2014-04-09T07:17:17Z
dc.date.available2014-04-09T07:17:17Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationPeng, X., Tong, B. M. K., Hirao, H., & Chiba, S. (2014). Inorganic-base-mediated hydroamination of alkenyl oximes for the synthesis of cyclic nitrones. Angewandte Chemie International Edition, 53(7), 1959-1962.en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10220/19197
dc.description.abstractA method based on hydroamination mediated by inorganic base was developed for the synthesis of cyclic nitrones from alkenyl oximes. DFT calculations of the reaction pathway suggested that this hydroamination could proceed through an unprecedented nucleophilic amination of the unactivated alkene by the oxime nitrogen atom. The transition state of this reaction is stabilized by an ionic interaction between a metal cation such as K+ and the oxime oxygen and negatively charged alkene moiety.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesAngewandte chemie international editionen_US
dc.rights© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry
dc.titleInorganic-base-mediated hydroamination of alkenyl oximes for the synthesis of cyclic nitronesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201308617


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