dc.contributor.authorZhu, Ming-Kui
dc.contributor.authorChen, Yu-Chen
dc.contributor.authorLoh, Teck-Peng
dc.date.accessioned2014-04-10T05:40:24Z
dc.date.available2014-04-10T05:40:24Z
dc.date.copyright2013en_US
dc.date.issued2013
dc.identifier.citationZhu, M.-K., Chen, Y.-C., & Loh, T.-P. (2013). Radical-mediated diamination of alkenes with phenylhydrazine and azodicarboxylates : highly diastereoselective synthesis of trans-diamines from cycloalkenes. Chemistry - A European Journal, 19(17), 5250-5254.en_US
dc.identifier.issn0947-6539en_US
dc.identifier.urihttp://hdl.handle.net/10220/19226
dc.description.abstractMetal-free synthesis: Diamination of alkenes by using phenylhydrazine and azodicarboxylates could be achieved in a one-pot manner under very mild conditions (see scheme; Boc=tert-butoxycarbonyl). This process works with the assistance of acetic acid by means of a radical mechanism and displays a high trans selectivity when cycloalkene substrates were used in the reaction.en_US
dc.language.isoenen_US
dc.relation.ispartofseriesChemistry - a European journalen_US
dc.rights© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry
dc.titleRadical-mediated diamination of alkenes with phenylhydrazine and azodicarboxylates : highly diastereoselective synthesis of trans-diamines from cycloalkenesen_US
dc.typeJournal Article
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doihttp://dx.doi.org/10.1002/chem.201203832


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